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Objective: To Prepare a table that includes materials & chemical reactions occurring at the anode and cathode of LCO, LMO, NCA, NMC, LFP, and LTO type of lithium-ion cells. Procedure: Introduction: Lithium-ion Cells are a secondary type of battery cell that is they are rechargeable and also they are reusable which makes…
Ramganesh Jothirenganathan
updated on 29 Dec 2020
Objective:
To Prepare a table that includes materials & chemical reactions occurring at the anode and cathode of LCO, LMO, NCA, NMC, LFP, and LTO type of lithium-ion cells.
Procedure:
Introduction:
Lithium-ion Cells are a secondary type of battery cell that is they are rechargeable and also they are reusable which makes them ideally suited for automotive applications and certain consumer electronics. When two or more cells connected together they are referred to as batteries. Like other batteries, Lithium-ion batteries also rely on the chemical energy stored in the bonds and atoms of elements and compounds and utilize this energy in a chemical reaction occurring inside the cell. The chemical energy from this reaction is converted to electrical energy and it is used. Since the Lithium-ion cells are rechargeable, they can perform the reverse reaction using electricity as well.
Construction:
Electrolyte:
Cathode and Anode:
Separator:
Current Collectors:
The following table gives the different types of Lithium-ion Batteries, Materials & chemical reactions occurring at the anode and cathode of LCO, LMO, NCA, NMC, LFP, and LTO type of lithium-ion cells.
Si.No | Type of Li-Ion Battery | Cathode | Anode | Electrolyte | Chemical Reaction |
1 | Lithium Cobalt Oxide(LCO) |
LiCoO2 |
LiC6 | LiPF6 in Ethylene Carbonate |
Anode: LixC6→xLi++xe-+C6 Cathode: Li1-xCoO2+xLi++xe-→LiCoO2 Redox Reaction: C6+LiCoO2↔LiC6+CoO2 |
2 | Lithium Manganese Oxide(LMO) |
LiMn2O4 |
LiC6 |
LiPF6 in Ethylene Carbonate |
Anode: LixC6→xLi++xe-+C6 Cathode: Li1-xMn2O4+xLi++xe-→LiMn2O4 Redox Reaction: C6+LiMn2O4↔LiC6+Mn2O4 |
3 |
Lithium Nickel Cobalt Aluminium Oxide(NCA) |
LiNiCoAlO2 |
LiC6 |
LiPF6 in Ethylene Carbonate |
Anode: LixC6→xLi++xe-+C6 Cathode: Li1-xNiCoAlO2+xLi++xe-→LiNiCoAlO2 Redox Reaction: C6+LiNiCoAlO2↔LiC6+NiCoAlO2 |
4 | Lithium Nickel Manganese Cobalt Oxide(NMC) |
LiNi0.8Mn0.1Co0.1O2 |
LiC6 |
LiPF6 in Ethylene Carbonate |
Anode: LixC6→xLi++xe-+C6 Cathode: Li1-xNi0.8Mn0.1Co0.1O2+xLi++xe-→LiNi0.8Mn0.1Co0.1O2 Redox Reaction: C6+LiNi0.8Mn0.1Co0.1O2↔LiC6+Ni0.8Mn0.1Co0.1O2 |
5 |
Lithium Iron Phosphate(LFP) |
LiFePO4 |
LiC6 |
LiPF6 in Ethylene Carbonate |
Anode: LixC6→ xLi++xe-+C6 Cathode: Li1-xFePO4+xLi++xe-→LiFePO4 Redox Reaction: C6+LiFePO4↔LiC6+FePO4 |
6 |
Lithium Titanium Oxide(LTO) |
LiMn2O4 |
Li4Ti5O12 |
LiPF6 in Ethylene Carbonate |
Anode: Li4Ti5O12→Ti5O12+4Li++4e- Cathode: 4Li1-xMn2O4+4Li++4e-→4LiMn2O4 Redox Reaction: Li4Ti5O12+4Mn2O4↔4LiMn2O4+Ti5O12 |
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