Challenge

Week 1 Understanding Different Battery Chemistry

Subjects Lithium cobalt oxide (LCO) Lithium Manganese oxide(LMO) Lithium nickel cobalt aluminium oxide (NCA) Lithium nickel manganese cobalt oxide (NMC) Lithium iron phosphate (LFP or LipO) Lithium Titanate (LTO)

Materials

Anode:- Graphite (C)

Cathode:- Lithium cobalt oxide (LiCoO2)

Anode:- Graphite (C)

Cathode:- Lithium Manganese oxide (LiMn2O2)

Anode:- Graphite (C)

Cathode:- Lithium nickel cobalt aluminium oxide (LiNiCoAlO2)

Anode:- Graphite (C)

Cathode:- Lithium nickel manganese cobalt oxide (LiNiMnCoO2)

Anode:- Graphite (C)

Cathode:- Lithium iron phosphate (LiFePO4)

Anode:- Lithium Titanate (LiTiO3)

Cathode:- Lithium manganese phosphate (LiMn2PO4)

Chemical Reaction
(Considering discharge cycle)

Anode:-

Li6 <-> C6 + Li+ + e-

Cathode:-

CoO2 + Li+ + e- <-> LiCoO2

Anode:-

Li6 <-> C6 + Li+ + e-

Cathode:-

MnO2 + Li+ + e- <-> LiMnO2

Anode:-

Li6 <-> C6 + Li+ + e-

Cathode:-

NiCoAlO2 + Li+ + e- <-> LiNiCoAlO2

Anode:-

Li6 <-> C6 + Li+ + e-

Cathode:-

NiMnCoO2 + Li+ + e- <-> LiNiMnCoO2

Anode:-

Li6 <-> C6 + Li+ + e-

Cathode:-

FePO4 + Li+ + e- <-> LiFePO4

Anode:-

Li4Ti5P12 + 4Li+ + 4e- <-> 4LiMn2O4

Cathode:-

4Mn2PO4 + 4Li+ + e- <-> 4LiMn2O4

Explanation

Anode:-

Graphite electrode gets oxidised when the load is connected and free lithium ion and electron released. Free electrons move in the direction opposite to the current direction and free lithium ion moves towards the cathode.

Cathode:-

when the load is connected, the current moves out from the cathode made up of Lithium cobalt oxide (LiCoO2) and the reduction process started. Free lithium ion gets attached to the cathode.

Anode:-

Graphite electrode gets oxidised when the load is connected and free lithium ion and electron released. Free electrons move in the direction opposite to the current direction and free lithium ion moves towards the cathode.

Cathode:-

when the load is connected, the current moves out from the cathode made up of Lithium Manganese oxide (LiMn2O2) and the reduction process started. Free lithium ion gets attached to the cathode.

Anode:-

Graphite electrode gets oxidised when the load is connected and free lithium ion and electron released. Free electrons move in the direction opposite to the current direction and free lithium ion moves towards the cathode.

Cathode:-

when the load is connected, the current moves out from the cathode made up of Lithium nickel cobalt aluminium oxide (LiNiCoAlO2) and the reduction process started. Free lithium ion gets attached to the cathode.

Anode:-

Graphite electrode gets oxidised when the load is connected and free lithium ion and electron released. Free electrons move in the direction opposite to the current direction and free lithium ion moves towards the cathode.

Cathode:-

when the load is connected, the current moves out from the cathode made up of Lithium nickel manganese cobalt oxide (LiNiMnCoO2) and the reduction process started. Free lithium ion gets attached to the cathode.

Anode:-

Graphite electrode gets oxidised when the load is connected and free lithium ion and electron released. Free electrons move in the direction opposite to the current direction and free lithium ion moves towards the cathode.

Cathode:-

when the load is connected, the current moves out from the cathode made up of Lithium iron phosphate (LiFePO4) and the reduction process started. Free lithium ion gets attached to the cathode.

Anode:-

Lithium Titanate (LiTiO3) electrode gets oxidised when the load is connected and free lithium ion and electron released. Free electrons move in the direction opposite to the current direction and free lithium ion moves towards the cathode.

Cathode:-

when the load is connected, the current moves out from the cathode made up of Lithium manganese phosphate (LiMn2PO4) and the reduction process started. Free lithium ion gets attached to the cathode.

Differences

Safety:- low thermal stability

Specific Power:- Low

Specific energy:- High (This allows them to deliver power over a relatively long period under low-load applications.)

Cost:- High (cobalt is fairly expensive)

Life Span:- short lifespan (500-1,000 cycles)

Performance:- High

Safety:- better thermal stability than LCO batteries

Specific Power:- High (charge quickly)

Specific energy:- Moderate

Cost:- High

Life Span:- low (300-700 charge cycles)

Performance:- low

Safety:- low

Specific Power:- Moderate

Specific energy:- High

Cost:- low

Life Span:- moderate

Performance:- High

Safety:- moderate

Specific Power:- moderate

Specific energy:- moderate to high

Cost:- low

Life Span:- moderate

Performance:- High

Safety:- Safe and highly stable (thermal runaway threshold is about 518 degrees Fahrenheit).

Specific Power:- Moderate

Specific energy:- low specific energy

Cost:- High

Life Span:- long life cycle (rating of 2,000 cycles or more)

Performance:- High Performance

Safety:- High (extremely wide operating temperature)

Specific Power:- High

Specific energy:- Low (stores a lower amount of energy relative to its weight)

Cost:- High

Life Span:- High

Performance:- High

Applications
  • mobile phones
  • tablets
  • laptops
  • cameras
  • portable power tools
  • medical instruments
  • some hybrid and electric vehicles
popular in the electric vehicle market. (tesla cars) power tools as well as electronic power-trains for e-bike, scooters, and some electric vehicles. Considered as the replacement of lead-acid batteries
  • Electric vehicles
  • charging stations
  • wind and solar energy storage
  • solar street lights
  • telecommunications systems
  • aerospace and military equipment
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