Challenge

Week 1 Understanding Different Battery Chemistry

Sl No LCO LMO NCA NMC LFP LTO
Full Form Lithium Cobalt Oxide Lithium ion manganese oxide battery Lithium Nickel Cobalt Aluminum Oxide Lithium Nickel Manganese Oxide Lithium Iron Phosphate Lithium Titanate Oxide
Short form Li-cobalt NMC LFP Li-Tritante
Cathode LiCoO2 LiMn2O4 LiNiCoAlO2 LiNiMnCoO2 LiFePO4 Li2TiO3
Anode Graphite Graphite Graphite Graphite Graphite Graphite
Reaction The cathode has a layered structure and during discharge, lithium ions move from the anode to the cathode. The flow reverses on charge The architecture forms a three-dimensional spinel structure that improves ion flow on the electrode, which results in lower internal resistance and improved current handling. A further advantage of spinel is high thermal stability and enhanced safety, but the cycle and calendar life are limited Shares similarities with NMC by offering high specific energy, reasonably good specific power and a long life span. Less flattering are safety and cost. Summarizes the six key characteristics. NCA is a further development of lithium nickel oxide; adding aluminum gives the chemistry greater stability. One of the most successful Li-ion systems is a cathode combination of nickel-manganese-cobalt (NMC). Similar to Li-manganese, these systems can be tailored to serve as Energy Cells or Power Cells. For example, NMC in an 18650 cell for moderate load condition has a capacity of about 2,800mAh and can deliver 4A to 5A This is made possible with nano-scale phosphate cathode material. The key benefits are high current rating and long cycle life, besides good thermal stability, enhanced safety and tolerance if abused. Batteries with lithium titanate anodes have been known since the 1980s. Li-titanate replaces the graphite in the anode of a typical lithium-ion battery and the material forms into a spinel structure. The cathode can be lithium manganese oxide or NMC.

And the graph will be as shown in below graph

By the graph will show the difference of Wh/kg and maximum will be of NCA and mimium of Lead Acid.

2 )

PFA different type of Lithium ion chemistry

Sl No Parameter Lithium Cobalt Oxide Lithium ion manganese oxide battery Lithium Nickel Cobalt Aluminum Oxide Lithium Nickel Cobalt Aluminium Oxide Lithium Titanate Oxide Lithium Iron phosphate
1 Nominal voltage 3.60V 3.70V (3.80V) 3.60V (3.70V) 3.20, 3.30V 2.40V 3.20,3.30
2 Full charge in v 4.20 4.20 4.20 or higher 4.20 2.85 3.65
3 Full Dischagre in V 3.00 3.0 3.0 3.0 1.80 2.50
4 Minimal Voltage in V 2.50 2.50 2.50 2.50 1.50 2.0
5 Specific Energy in Wh/kg 150-200 100-150 150-220 200-260 70-80 90-120
6 Charge Rate 0.7-1C(3h) 0.7-1C(3h) 0.7-1C(3h) 1C 1C(5Cmax) 1C(3h)
7 Dischagre Rate 1C(1h) 1C,10C possible 1-2C 1C 10C possible 1C(25C pulse)
8 Cycle Life 500-1000 300-700 1000-2000 50 3000-7000 1000-2000
9 Thermal RunAway 150 C 250 C 210 C 270 C 500 C 210 C
10 Application Mobile Phones ,Tablets. Power Train,Power Tools. E-Bike ,Medical Devies. Medical ,EV(Tesla). UPS,EV,Solar Street . Stationary with high Currents and Endurance .
11 Comments High energy,limited market. Higher Power ,Less Capacity. High Capacity & HighPower. Higest capacity with Moderate Power. Long Life,Wide Temperature.Low capacity .Very Expensive. Flat Discharge ,High power ,safe.

Sources

1 battery university

2 From internet

3 From DIY battery from john.

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