Challenge

Week 1 Understanding Different Battery Chemistry

Abbreviation Name Chemical Name Anode Cathode Anode Reaction Cathode Reaction Full Reaction Year Application
LCO Lithium Cobalt Oxide LiCoO2 Graphite Carbon Cobalt Oxide - LiCoO2 (~ 60% Co) LiC6 ↔ C6 + Li+ + e– CoO2 + Li+ + e– ↔ LiCoO2 LiC6 + CoO2 ↔ C6 + LiCoO2 1991 Mobile Phones, Laptops, Cameras
LMO Lithium Manganese Oxide LiMn2O4 Graphite Carbon Manganese Oxide - LiMn2O4 LiC6 ↔ C6 + Li+ + e– Mn2O4 + Li+ + e- ↔ LiMn2O4 LiC6 + Mn2O4 ↔ C6 + LiMn2O4 1996 Power Tool, Medical Devices, Electric Powertrains
NCA Lithium Nickel Cobalt Aluminium Oxide LiNiCoAlO2 Graphite Carbon Nickel Cobalt Aluminium Oxide - LiNiCoAlO2 LiC6 ↔ C6 + Li+ + e– NiCoAlO2 + Li+ + e- ↔ LiNiCoAlO2 LiC6 + NiCoAlO2 ↔ C6 +LiNiCoAlO2 1999 Medical Devices, Industrial Electric Powertrains
NMC Lithium Nickel Manganese Cobalt Oxide LiNiMnCoO2 Graphite Carbon Nickel Manganese Cobalt Oxide - LiNiMnCoO2 LiC6 ↔ C6 + Li+ + e– NiMnCoO2 + Li+ + e- ↔ LiNiMnCoO2 LiC6 + NiMnCoO2 ↔ C6 + LiNiMnCoO2 2008 E-Bikes, Medical Device, EV's
LFP Lithium Iron Phosphate LiFePO4 Graphite Carbon Iron Phosphate - LiFePO4 LiC6 ↔ C6 + Li+ + e– FePO4 + Li+ + e- ↔ LiFePO4 LiC6 + FePO4 ↔ C6 + LiFEPO4 1996 Suitable for High Load Current and Endurance application
LTO Lithium Titanate Li2TiO3 Titanate - Li2TiO3 Lithium Manganese Oxide or NMC Li2TiO3 ↔ TiO3 + 2Li+ + 2e- Mn2O4 + Li+ + e- ↔ LiMn2O4 Li2TiO3 + 2Mn2O4 ↔ TiO3 + 2LiMn2O4 2008 UPS, Solar Power Lights, Electric Powertrain

Cell Electrical & Thermal Properties

Abbreviation Voltage Operating Range Specific Energy Charge Discharge Cycle Life Thermal Runaway
LCO 3.6V Nominal 3.0-4.2 V/Cell 150-200 Wh/Kg 0.7-1C 1C 500-1000 150 Degree Centigrade
LMO 3.8V Nominal 3.0-4.2 V/Cell 100-150 Wh/Kg 0.7-1C 1C 300-700 250 Degree Centigrade
NCA 3.6V Nominal 3.0-4.2 V/Cell 200-60 Wh/Kg 0.7C 1C 500 150 Degree Centigrade
NMC 3.7V Nominal 3.0-4.2 V/Cell 150-220 Wh/Kg 0.7-1C 1C 1000-2000 210 Degree Centigrade
LFP 3.3V Nominal 2.5-3.65 V/Cell 90-120 Wh/Kg 1C 1C >2000 270 Degree Centigrade
LTO 2.4V Nominal 1.8-2.85 V/Cell 50-80 Wh/Kg 1C 10C 3000-7000 Safest Battery

Cell Rating Scale (0 to 5) -

Cell Type Cost Specific Energy Specific Power Safety Life Span Performance
NCA 3 5 5 2 5 4
NMC 4 5 4 4 4 4
LTO 2 3 4 5 5 5
LiFePO4 4 3 4 5 5 4
LMO 4 4 4 4 3 3

In Cost - Low Points means high price.

Working of a Li Battery

During discharging of the cell, the lithium ions move from Anode to Cathode through electrolyte while the electrons move in the same direction but through the external circuit. While charging, the reverse occurs with Lithium ions and electrons moving back to Anode.

Always check for SEI (Solid Electrolyte Interface) Layer for performance.

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